Introduces the Spectral Channel Attention Network (SCAN), a deep learning approach designed to improve cloud and cloud shadow detection in hyperspectral imagery from MethaneSAT and MethaneAIR. By dynamically weighting individual spectral bands based on their physical relevance, rather than treating all wavelengths equally, SCAN outperforms traditional U-Net and transformer-based attention models on MethaneSAT data, improving F1-scores and shadow detection accuracy. When combined with spatial models in an ensemble framework, the approach achieves state-of-the-art performance, directly strengthening the reliability of satellite-based methane retrievals worldwide.